Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene
Following the measurements of UV and mid-IR spectra of cyanodiacetylene, H-CC2-CN, isolated in low temperature Ar matrices, the first photochemical study on this compound and on its 2H isotopomer was carried out with the laser light tuned to 267 nm and with far-UV discharge lamps. Evidence for the formation of isocyanodiacetylene, H-CC2-CN, was found in infrared absorption spectra interpreted with the aid of available theoretical predictions.
Full text: J. Chem. Phys. 126 (2007) 164301
Tags: Ar matrix, isomers, molecular spectroscopy, UV spectra, vibrational spectroscopy
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